| Brass |
Potable water, treated water, compressed air, inert gases, and many non-aggressive oils. |
Indoor plumbing, utility services, moderate humidity, and general industrial service. |
Approximately -20°C to 150°C, depending on alloy, design, pressure rating, and seals. |
Good machinability, relatively low cost, reliable sealing surfaces, and good resistance to ordinary water corrosion. |
Not recommended for ammonia, some aggressive chemicals, high-chloride water, or applications with a risk of dezincification unless a suitable dezincification-resistant alloy is specified. |
Water isolation, instrument air, small-diameter utility lines, and general-purpose ball or gate valves. |
| Bronze |
Fresh water, seawater in selected grades, steam, and many general industrial fluids. |
Marine, plumbing, shipboard, and moderately corrosive service environments. |
Approximately -20°C to 200°C, subject to alloy, pressure class, trim, and seat material. |
Better resistance to many water-related corrosion conditions than ordinary brass; good casting performance and durability. |
Compatibility varies significantly by bronze alloy. Verify suitability for strong acids, strong alkalis, ammonia, and high-velocity seawater. |
Marine water lines, building services, boiler auxiliaries, and low-to-medium pressure utility systems. |
| Carbon Steel |
Hydrocarbons, fuel oils, natural gas, steam, and many non-corrosive industrial liquids and gases. |
High mechanical loads, industrial piping, outdoor installations, and high-pressure service when properly protected. |
Approximately -29°C to 425°C for many designs; low-temperature toughness and elevated-temperature strength must be checked. |
High strength, good resistance to mechanical shock, and suitability for larger sizes and higher pressures. |
Corrodes readily in wet or oxygenated environments without coating, lining, corrosion allowance, or suitable water treatment. |
Process utilities, steam systems, fuel systems, compressed gases, and oil and gas piping. |
| Stainless Steel 316/316L |
Deionized water, many chemicals, food and pharmaceutical fluids, seawater exposure, and clean gases. |
Corrosive atmospheres, washdown areas, sanitary installations, and applications requiring low contamination. |
Approximately -196°C to 400°C for the metal body in suitable designs; seats and packing may impose lower limits. |
Strong general corrosion resistance, good performance in chloride-containing environments compared with 304 stainless steel, and good cleanability. |
Not universally resistant to concentrated chlorides, hydrochloric acid, reducing acids, or crevice corrosion. Stress-corrosion cracking can occur under certain chloride and temperature conditions. |
Chemical processing, food and beverage lines, marine service, laboratory utilities, and high-purity systems. |
| Cast Iron |
Cooling water, HVAC water, non-corrosive liquids, and low-pressure air service. |
Building services, water treatment, and stationary indoor or protected outdoor installations. |
Typically about 0°C to 230°C, depending on valve design, lining, pressure class, and thermal cycling. |
Cost-effective for large valve sizes, good compressive strength, and useful vibration-damping characteristics. |
Brittle compared with steel and vulnerable to impact, freezing water, rapid temperature changes, and corrosive fluids unless lined or protected. |
Chilled-water systems, HVAC isolation, fire-protection auxiliaries, and municipal water systems. |
| Ductile Iron |
Water, wastewater, cooling water, and selected mildly corrosive process fluids. |
Buried pipelines, municipal systems, water treatment plants, and large-diameter services. |
Commonly about -20°C to 230°C, but the actual limit is controlled by the valve design, lining, and elastomer. |
Higher impact toughness and tensile strength than ordinary cast iron, with good value for larger valve sizes. |
Requires protective coatings or linings for many corrosive services. Elastomer compatibility and external corrosion protection must be evaluated. |
Water distribution, wastewater treatment, pumping stations, and cooling-water networks. |
| PVC |
Water, dilute acids, dilute alkalis, salts, and many aqueous chemical solutions. |
Lightweight, non-metallic piping, ambient-temperature chemical handling, and corrosive wet environments. |
Approximately 0°C to 60°C for many pressure applications; allowable pressure generally decreases as temperature rises. |
Excellent resistance to many aqueous chemicals, low weight, no galvanic corrosion, and simple installation. |
Limited resistance to heat, impact, aromatic hydrocarbons, ketones, and some concentrated chemicals. Avoid freezing service and excessive mechanical loading. |
Water treatment, chemical dosing, irrigation, swimming pools, and low-temperature process lines. |
| CPVC |
Hot water, chlorinated water, dilute acids, dilute alkalis, and selected corrosive aqueous fluids. |
Warm corrosive service where a non-metallic valve is preferred and pressure requirements are moderate. |
Approximately 0°C to 90°C, with pressure derating required at elevated temperature. |
Higher temperature capability than standard PVC and good resistance to many aqueous chemicals. |
Can be attacked by certain solvents and organic chemicals; brittle behavior, thermal expansion, and joint compatibility must be considered. |
Hot-water distribution, chemical drainage, water treatment, and corrosive utility lines. |
| PTFE-Lined Metal |
Strong acids, strong alkalis, solvents, corrosive chemicals, and high-purity chemical fluids when compatibility is confirmed. |
Highly corrosive process environments where the metal body provides mechanical strength and the lining provides chemical resistance. |
Often approximately -20°C to 180°C, depending on PTFE grade, lining construction, pressure, and thermal cycling. |
Very broad chemical resistance, low friction, and protection of the structural metal body from the process fluid. |
Limited resistance to mechanical damage, permeation, rapid temperature changes, and certain molten alkali metals or fluorine-related services. Lining integrity is critical. |
Chemical processing, acid transfer, corrosive wastewater, and aggressive laboratory or industrial services. |
| Alloy 20 or Comparable Corrosion-Resistant Alloy |
Sulfuric acid and selected aggressive chemical services where standard stainless steel is inadequate. |
Specialized chemical processing with demanding corrosion conditions and controlled operating parameters. |
Commonly suitable for moderate to elevated temperatures; the exact limit depends on alloy, concentration, pressure, and valve construction. |
Improved resistance to certain sulfuric-acid and chemical environments compared with common stainless steels. |
Higher cost and not a universal solution. Corrosion rates depend strongly on acid concentration, temperature, impurities, and flow velocity. |
Acid handling, chemical reactors, fertilizer production, and specialized process lines. |